MATERIAL SAFETY DATA SHEET
Section I: Preparation information
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MANUFACTURED FOR: DATE PREPARED: FEB 15, 2002
BLANDING INTERNATIONAL GROUP, LLC
3800 NEBRASKA
TAMPA, FL 33613
24-HOUR EMERGENCY: CALL 1-800-ASHLAND OR 1-800-274-5263
(ASK ABOUT PRODUCT CODE NUMBER 1310)
Section II: Product Information
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PRODUCT NAME: BGM - GREEN EXTREME HFO
GENERAL/GENERIC NAME: SOLVENT BLEND
PRODUCT USE: FUEL CONDITIONER FOR HYDROCARBON FUELS
WHMIS CLASSIFICATION: B3 D2B
DSL STATUS: ON DSL
Section III: Shipping information
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SHIPPING NOT REGULATED AS DANGEROUS GOODS FOR SHIPPING
UN NUMBER: N/A
CLASS: N/A
PACKING GROUP: N/A
Section IV: Hazardous Ingredient (s)
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INGREDIENT: % W/W TLV CAS No.
NAPHTHA PETROLEUM 60-100 100 PPM(*) 64742-94-5
NAPHTHALENE 3-7 10 PPM 91-20-3
ORGANOMETALLIC COMPOUNDS 1-5 10 MG / M3 N/A (BLEND)
1,2,4 TRIMETHYLBENZENE 0.1-1 25 PPM 95-63-6
Section V: Physical Data
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INITIAL BOIL-POINT: 158 °C OR 316 °F @ 760 MMHG
VAPOUR PRESSURE: 3.75 MMHG @ 38 °C OR 100 °F
VAPOUR DENSITY: HEAVIER THAN AIR
EVAPORATION RATE: SLOWER THAN ETHER
PHYSICAL STATE: LIQUID
ODOUR THRESHOLD: N/E
FREEZING POINT: N/E
SPECIFIC GRAVITY: 0.89 @ 20 °C OR 68 °F
% VOLATILE: 100 %
APPEARANCE AND ODOUR: CLEAR YELLOW LIQUID, AROMATIC ODOUR
Section VI: Fire & Explosion Information
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FLASH POINT: CLOSED CUP 62.8 C OR 145 F
FLAMMABLE LIMITS: LFL: 0.9% UFL: 6.0%
AUTO IGNITION TEMPERATURE: N/E
EXTINGUISHING MEDIA: FOAM, WATER FOG, DRY CHEMICAL,
OR CARBON DIOXIDE
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE, VAROUS HYDROCARBONS, ETC.
FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE
OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES.
SPECIAL FIRE & EXPLOSION HAZARDS:
VAPOURS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY HEAT, PILOT LIGHTS, OTHER FLAMES AND IGNITION SOURCES AT LOCATIONS DISTANT FROM DATERIAL HANDING POINT.
NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY)
BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY.
ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDED AND/OR BONDED WHEN MATERIAL IS TRANSFERRED.
SECTION VII TOXICOLOGICAL PROPERTIES
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THRESHOLD LIMIT VALUE: SEE SECTION IV
EFFECTS OF ACUTE OVEREXPOSURE:
EYES: MAY CAUSE SEVERE IRRITAION, REDNESS, TEARING BLURRED
VISION
SKIN: MAY CAUSE IRRITATION.
BREATHING: EXCESSIVE INHALATION OF VAPOURS MAY CAUSE NASAL
AND RESPIRATIORY IRRIATION
SWALLOWING: CAN CAUSE GASTROINTESTINAL IRRETATION, NAUSEA,
VOMITING AND DIARRHEA. ASPIRATION OF MATERIAL INTO
LUNGS CAN CASUE CHEMICAL PNEUMONITIS, WHICH CAN BE
FATAL.
OTHER DATA:
SOLVENT NAPHTHA LD:50 (ORL-RAT) 3000 MG / KG
(PETROLEUM) HEAVY LD: 50 (SKN-RBT) 3000 MG / KG
AROMATIC LC: 50 (INH-RAT) >3800 MG / M3 / 4H
NAPHTHALENE: LD:50 (ORL-RAT) >490 MG / KG
LD:50 (SKN-RBT) >20 G / KG
LC:50 (INH-RAT) >340 MG /M3 / 4H
1,2,4 TRIMETHYLBENZENE: LD:50 (ORL-RAT) 6G / KG
LD:50 (SKN-RBT) NOT ESTABLISHED
LC:50 (INH-RAT) 18 MG /M3 / 4H
ORGANOMETALLICS: LD:50 (ORL-RAT) 1320 MG / KG
LD:50 (SKN-RBT) 3000 MG / KG
LC:50 (INH-RAT) >150 MG /M3 / 4H
SECTION VIII: FIRST AID MEASURES
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FIRST AID:
IF ON SKIN –
THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
IF IN EYES –
FLUSH WITH LARGE AMOUNTS OF WATER, LIFTING UPPER AND LOWER LIDS
OCCASIONALLY; GET MEDICAL ATTENTION.
IF SWALLOWED –
DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET AND GET MEDICAL
ATTENTION.
IF INHALEDIF
AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT,
ADMINISTER OXYGEN. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION.
KEEP PERSON WARM, QUIET AND GET MEDICAL ATTENTION.
SECTION IX: REACTIVITY DATA
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HAZARDOUS POLYMERIZATION:
CANNOT OCCUR
STABILITY:
STABLE
INCOMPATIBILITY:
AVOID CONTACT WITH STRONG OXIDIZING AGENTS, SULFURIC ACIC,
NITRIC ACID
HAZARDOUS DECOMPOSITION PRODUCTS:
NOT APPLICABLE
SECTION X: PREVENTIVE MEASURES
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STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED:
SMALL SPILL:
ABSORB ONTO SAND OR OTHER ABSORBANT MATERIAL.
LARGE SPILL:
ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES INCLUDING PILOT LIGHTS,
ELECTRICAL SPARKS). PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD
BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN UP HAS BEEN COMPLETED. STOP
SPILL AT SOURCE; DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP LIQUID TO
SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH,
FLOOR ABSORBANT, OR OTHER ABSORVENT MATERIAL AND SHOVELED INTO
CONTAINERS.
WASTE DISPOSAL METHOD:
SMALL SPILL:
DEPOSIT IN A LANDFILL IN ACCORDANCE WITH ALL LOCAL, PROVINCIAL AND
FEDERAL REGULATIONS.
LARGE SPILL:
DESTROY BY INCENERATION IN ACCORDANCE WITH ALL LOCAL, PROVINCIAL AND
FEDERAL REGULATIONS.
RESPIRATORY PROTECTION:
IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY COMPONENT IS
EXCCEEDED (SEE SECTION IV) A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR
IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA
REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE
PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR SAFETY EQUIPMENT
SUPPLIER) ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE
IMPLEMENTED TO REDUCE EXPOSURE.
VENTILATION:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
PROTECTIVE GLOVES:
WEAR RESISTANT GLOVES, SUCH AS POLYETHYLENE.
EYE PROTECTION:
CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA
REGULATIONS ARE ADVISED; HOWEVER, OSHA REGULATION ALSO
PERMIT OTHER TYPE SAFETY CLASSES. (CONSULT YOUR SAFETY
EQUIPMENT SUPPLIER)
OTHER PROTECTIVE EQUIPMENT:
TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR
IMPERVIOUS CLOTHING AND BOOTS.
PRODUCT DISPOSAL INFORMATION:
THIS PRODUCT MAY BE CLASSIFED AS A LIQUID INDUSTRIAL WASTE OR
A REGISTERABLE SOLID WASTE AND MAY BE SUBJECT TO WASTER
GENERATOR REQUIREMENTS.
CONTAINERS OF THIS MATERIAL MAY BE HAXARDOUS WHEN EMPTIED.
SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR,
LIQUID, AND / OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THE
DATA SHEET MUST BE OBSERVED.
METAL AND PLASTIC CONTAINERS MAY BE RECYCLED. PLEASE
CONTACT YOUR DRUM RECONDITIONER FOR FURTHER INFORMATION.
THE INFORMATION PRESENTED HEREIN IS BELIEVED TO BE ACCURATE,
BUT IS NOT WARRANTED TO BE, WHETHER ORIGINATING WITH THE
COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFRM, IN ADVANCE
OF NEED, THAT THE INFORMATION IS CURRENT, APPLICABLE, AND
SUITABLE TO THEIR CIRCUMSTANCES.
Note: * Recommended
N/E – Not Established
N/A – Not Applicable